1.14.19.65: (S)-cheilanthifoline synthase
This is an abbreviated version!
For detailed information about (S)-cheilanthifoline synthase, go to the full flat file.
Word Map on EC 1.14.19.65
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1.14.19.65
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stylopine
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eschscholzia
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californica
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coptis
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japonica
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sanguinarine
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berberine
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s-tetrahydrocolumbamine
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benzophenanthridine
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isoquinoline
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6-hydroxylase
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cyp80b1
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argemone
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benzylisoquinoline
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poppy
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s-scoulerine
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mexicana
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protopine
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pharmacology
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synthesis
- 1.14.19.65
- stylopine
-
eschscholzia
- californica
- coptis
- japonica
- sanguinarine
- berberine
-
s-tetrahydrocolumbamine
-
benzophenanthridine
- isoquinoline
-
6-hydroxylase
- cyp80b1
-
argemone
-
benzylisoquinoline
- poppy
-
s-scoulerine
- mexicana
- protopine
- pharmacology
- synthesis
Reaction
Synonyms
(S)-scoulerine oxidase (methylenedioxy-bridge-forming), cheilanthifoline synthase, CYP719A13, CYP719A14, CYP719A5, EC 1.1.3.33, EC 1.14.21.2, S-cheilanthifoline synthase, synthase, (S)-cheilanthifoline
ECTree
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Substrates Products
Substrates Products on EC 1.14.19.65 - (S)-cheilanthifoline synthase
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REACTION DIAGRAM
(S)-coreximine + [reduced NADPH-hemoprotein reductase] + O2
(S)-cheilanthifoline + [oxidized NADPH-hemoprotein reductase] + H2O
kcat (S)-coreximine: 1% compared to kcat (S)-cheilanthifoline: 100%
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-
?
(S)-scoulerine + [reduced NADPH-hemoprotein reductase] + O2
(S)-cheilanthifoline + [oxidized NADPH-hemoprotein reductase] + 2 H2O
(S)-scoulerine + [reduced NADPH-hemoprotein reductase] + O2
(S)-cheilanthifoline + [oxidized NADPH-hemoprotein reductase] + H2O
(S)-scoulerine + [reduced NADPH-hemoprotein reductase] + O2
(S)-nandinine + [oxidized NADPH-hemoprotein reductase] + H2O
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-
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?
(S)-cheilanthifoline + [oxidized NADPH-hemoprotein reductase] + 2 H2O
high substrate specificity
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-
?
(S)-scoulerine + [reduced NADPH-hemoprotein reductase] + O2
(S)-cheilanthifoline + [oxidized NADPH-hemoprotein reductase] + 2 H2O
the enzyme is involved in biosynthesis of stylopine
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-
?
(S)-cheilanthifoline + [oxidized NADPH-hemoprotein reductase] + H2O
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-
-
?
(S)-scoulerine + [reduced NADPH-hemoprotein reductase] + O2
(S)-cheilanthifoline + [oxidized NADPH-hemoprotein reductase] + H2O
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-
-
-
?
(S)-scoulerine + [reduced NADPH-hemoprotein reductase] + O2
(S)-cheilanthifoline + [oxidized NADPH-hemoprotein reductase] + H2O
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NADPH is essential for activity, NADH displays only 0.5% turnover of that of NADPH
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?
(S)-scoulerine + [reduced NADPH-hemoprotein reductase] + O2
(S)-cheilanthifoline + [oxidized NADPH-hemoprotein reductase] + H2O
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enzyme is induced 20 h after challenging the cell suspension cultur with elicitor
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?