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Literature summary for 4.1.2.19 extracted from

  • Camps Bres, F.; Guerard-Hélaine, C.; Hélaine, V.; Fernandes, C.; Sanchez-Moreno, I.; Traikia, M.; Garcia-Junceda, E.; Lemaire, M.
    L-Rhamnulose-1-phosphate and L-fuculose-1-phosphate aldolase mediated multi-enzyme cascade systems for nitrocyclitol synthesis (2015), J. Mol. Catal. B, 114, 50-57 .
No PubMed abstract available

Cloned(Commentary)

Cloned (Comment) Organism
expressed in Escherichia coli BL21(DE3) cells Escherichia coli

Natural Substrates/ Products (Substrates)

Natural Substrates Organism Comment (Nat. Sub.) Natural Products Comment (Nat. Pro.) Rev. Reac.
L-Rhamnulose 1-phosphate Escherichia coli
-
Glycerone phosphate + (S)-lactaldehyde
-
?

Organism

Organism UniProt Comment Textmining
Escherichia coli
-
-
-

Purification (Commentary)

Purification (Comment) Organism
Ni-NTA column chromatography Escherichia coli

Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
(2R)-2,3-dihydroxy-4-nitrobutanal
-
Escherichia coli (1R,2R,3S,4R,5S,6S)-1-hydroxymethyl-6-nitrocyclohexane-1,2,3,4,5-pentol + (1S,2R,3R,4R,5R,6R)-1-hydroxymethyl-6-nitrocyclohexane-1,2,3,4,5-pentol
-
r
(2S)-2,3-dihydroxy-4-nitrobutanal
-
Escherichia coli (1R,2R,3S,4S,5S,6S)-1-hydroxymethyl-6-nitrocyclohexane-1,2,3,4,5-pentol + 1-hydroxymethyl-6-nitrocyclohexane-1,2,3,4,5-pentol
-
r
3-hydroxy-4-nitrobutanal
-
Escherichia coli (1R,2R,3S,5R,6S)-1-hydroxymethyl-6-nitrocyclohexane-1,2,3,5-tetraol + (1S,2R,3R,5S,6R)-1-hydroxymethyl-6-nitrocyclohexane-1,2,3,5-tetraol
-
r
4-nitrobutanal
-
Escherichia coli (1R,2R,3S,6S)-1-hydroxymethyl-6-nitrocyclohexane-1,2,3-triol + (1S,2R,3R,6R)-1-hydroxymethyl-6-nitrocyclohexane-1,2,3-triol
-
?
dimethoxyacetaldehyde + glycerone phosphate
-
Escherichia coli (3R,4R)-3,4-dihydroxy-5,5-dimethoxy-2-oxopentyl phosphate
-
?
L-Rhamnulose 1-phosphate
-
Escherichia coli Glycerone phosphate + (S)-lactaldehyde
-
?

Synonyms

Synonyms Comment Organism
L-Rhamnulose-1-phosphate aldolase
-
Escherichia coli
RhuA
-
Escherichia coli