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Literature summary for 4.1.1.5 extracted from

  • Drake, A.F.; Siligardi, G.; Crout, D.H.G.; Rathbone, D.L.
    Applications of vibrational infrared circular dichroism to biological problems: stereochemistry of proton exchange in acetoin (3-hydroxybutan-2-one) catalyzed by acetolactate decarboxylase (1987), J. Chem. Soc. Chem. Commun., 1987, 1834-1835.
No PubMed abstract available

Organism

Organism UniProt Comment Textmining
Bacillus sp. (in: Bacteria)
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Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
2-Hydroxy-2-methyl-3-oxobutanoate
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Bacillus sp. (in: Bacteria) (R)-3-Hydroxybutan-2-one + CO2
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additional information the enzyme in D2O induces a D/H exchange in (R)-acetoin and not the (S)-isomer to give a deuteriated product with retention of configuration Bacillus sp. (in: Bacteria) ?
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