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Literature summary for 4.1.1.5 extracted from

  • Hill, R.K.; Sawada, S.; Arfin, S.M.
    Stereochemistry of valine and isoleucine biosynthesis. IV. Synthesis, configuration, and enzymatic specificity of alpha-acetolactate and alpha-aceto-alpha-hydroxybutyrate (1979), Bioorg. Chem., 8, 175-189.
No PubMed abstract available

Organism

Organism UniProt Comment Textmining
Acidobacterium aerogenes
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Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
2-Hydroxy-2-ethyl-3-oxobutanoate specifically decarboxylates the (S)-enantiomer Acidobacterium aerogenes 3-Hydroxypentan-2-one + CO2
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2-Hydroxy-2-methyl-3-oxobutanoate specifically decarboxylates the S-enantiomer, forming (R)-acetoin with inversion of configuration Acidobacterium aerogenes (R)-3-Hydroxybutan-2-one + CO2
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