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Literature summary for 1.17.1.9 extracted from

  • Ikeyama, S.; Amao, Y.
    An artificial co-enzyme based on the viologen skeleton for highly efficient CO2 reduction to formic acid with formate dehydrogenase (2017), ChemCatChem, 9, 833-838.
No PubMed abstract available
Search for more literature for 1.17.1.9

KM Value [mM]

KM Value [mM] KM Value Maximum [mM] Substrate Comment Organism Structure
0.017
-
 reduced 1,1'-diaminoethyl-4,4'-bipyridinium salt at pH 7.4, temperature not specified in the publication [Candida] boidinii
0.118
-
 reduced 1-methyl-1'-aminoethyl-4,4'-bipyridinium salt at pH 7.4, temperature not specified in the publication [Candida] boidinii
0.212
-
 reduced methyl viologen at pH 7.4, temperature not specified in the publication [Candida] boidinii
0.292
-
 reduced 1-methyl-1'-carboxymethyl-4,4'-bipyridinium salt at pH 7.4, temperature not specified in the publication [Candida] boidinii
0.371
-
 reduced 1,1'-dicarboxyl-4,4'-bipyridinium salt at pH 7.4, temperature not specified in the publication [Candida] boidinii

Natural Substrates/ Products (Substrates)

Natural Substrates Organism Comment (Nat. Sub.) Natural Products Comment (Nat. Pro.) Rev. Reac.
CO2 + NADH [Candida] boidinii
-
 formate + NAD+
-
 ?

Organism

Organism UniProt Comment Textmining
[Candida] boidinii O13437
-
-

Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
CO2 + NADH
-
 [Candida] boidinii formate + NAD+
-
 ?
CO2 + reduced 1,1'-diaminoethyl-4,4'-bipyridinium salt
-
 [Candida] boidinii formate + 1,1'-diaminoethyl-4,4'-bipyridinium salt
-
 ?
CO2 + reduced 1,1'-dicarboxyl-4,4'-bipyridinium salt
-
 [Candida] boidinii formate + 1,1'-dicarboxyl-4,4'-bipyridinium salt
-
 ?
CO2 + reduced 1,1'-diphenyl-4,4'-bipyridinium salt
-
 [Candida] boidinii formate + 1,1'-diphenyl-4,4'-bipyridinium salt
-
 ?
CO2 + reduced 1-methyl-1'-aminoethyl-4,4'-bipyridinium salt
-
 [Candida] boidinii formate + 1-methyl-1'-aminoethyl-4,4'-bipyridinium salt
-
 ?
CO2 + reduced 1-methyl-1'-carboxymethyl-4,4'-bipyridinium salt
-
 [Candida] boidinii formate + 1-methyl-1'-carboxymethyl-4,4'-bipyridinium salt
-
 ?
CO2 + reduced methyl viologen
-
 [Candida] boidinii formate + methyl viologen
-
 ?

Synonyms

Synonyms Comment Organism
FDH
-
 [Candida] boidinii

Turnover Number [1/s]

Turnover Number Minimum [1/s] Turnover Number Maximum [1/s] Substrate Comment Organism Structure
0.005
-
 reduced 1,1'-dicarboxyl-4,4'-bipyridinium salt at pH 7.4, temperature not specified in the publication [Candida] boidinii
0.025
-
 reduced 1-methyl-1'-carboxymethyl-4,4'-bipyridinium salt at pH 7.4, temperature not specified in the publication [Candida] boidinii
0.032
-
 reduced methyl viologen at pH 7.4, temperature not specified in the publication [Candida] boidinii
0.038
-
 reduced 1-methyl-1'-aminoethyl-4,4'-bipyridinium salt at pH 7.4, temperature not specified in the publication [Candida] boidinii
0.072
-
 reduced 1,1'-diaminoethyl-4,4'-bipyridinium salt at pH 7.4, temperature not specified in the publication [Candida] boidinii

Cofactor

Cofactor Comment Organism Structure
NAD+
-
 [Candida] boidinii

kcat/KM [mM/s]

kcat/KM Value [1/mMs-1] kcat/KM Value Maximum [1/mMs-1] Substrate Comment Organism Structure
0.09
-
 reduced 1-methyl-1'-carboxymethyl-4,4'-bipyridinium salt at pH 7.4, temperature not specified in the publication [Candida] boidinii
0.15
-
 reduced methyl viologen at pH 7.4, temperature not specified in the publication [Candida] boidinii
0.32
-
 reduced 1-methyl-1'-aminoethyl-4,4'-bipyridinium salt at pH 7.4, temperature not specified in the publication [Candida] boidinii
1.55
-
 reduced 1,1'-dicarboxyl-4,4'-bipyridinium salt at pH 7.4, temperature not specified in the publication [Candida] boidinii
4.17
-
 reduced 1,1'-diaminoethyl-4,4'-bipyridinium salt at pH 7.4, temperature not specified in the publication [Candida] boidinii