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Literature summary for 1.14.12.18 extracted from

  • Seo, J.; Kang, S.I.; Won, D.; Kim, M.; Ryu, J.Y.; Kang, S.W.; Um, B.H.; Pan, C.H.; Ahn, J.H.; Chong, Y.; Kanaly, R.A.; Han, J.; Hur, H.G.
    Absolute configuration-dependent epoxide formation from isoflavan-4-ol stereoisomers by biphenyl dioxygenase of Pseudomonas pseudoalcaligenes strain KF707 (2011), Appl. Microbiol. Biotechnol., 89, 1773-1782.
    View publication on PubMed

Cloned(Commentary)

Cloned (Comment) Organism
expressed in Escherichia coli JM109 cells Pseudomonas oleovorans

Natural Substrates/ Products (Substrates)

Natural Substrates Organism Comment (Nat. Sub.) Natural Products Comment (Nat. Pro.) Rev. Reac.
biphenyl + NADH + H+ + O2 Pseudomonas oleovorans
-
2,3-dihydro-dihydroxybiphenyl + NAD+
-
?
biphenyl + NADH + H+ + O2 Pseudomonas oleovorans KF707
-
2,3-dihydro-dihydroxybiphenyl + NAD+
-
?

Organism

Organism UniProt Comment Textmining
Pseudomonas oleovorans
-
-
-
Pseudomonas oleovorans KF707
-
-
-

Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
(3R,4R)-cis-isoflavan-4-ol + NADH + H+ + O2
-
Pseudomonas oleovorans (3R,4R)-3-(7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-yl)-3,4-dihydro-2H-chromen-4-ol + NAD+
-
?
(3R,4R)-cis-isoflavan-4-ol + NADH + H+ + O2
-
Pseudomonas oleovorans KF707 (3R,4R)-3-(7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-yl)-3,4-dihydro-2H-chromen-4-ol + NAD+
-
?
(3R,4S)-trans-isoflavan-4-ol + NADH + H+ + O2
-
Pseudomonas oleovorans (3R,4S)-3-(7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-yl)-3,4-dihydro-2H-chromen-4-ol + NAD+
-
?
(3R,4S)-trans-isoflavan-4-ol + NADH + H+ + O2
-
Pseudomonas oleovorans KF707 (3R,4S)-3-(7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-yl)-3,4-dihydro-2H-chromen-4-ol + NAD+
-
?
(3S,4R)-trans-isoflavan-4-ol + NADH + H+ + O2
-
Pseudomonas oleovorans (3S,4R)-3-(7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-yl)-3,4-dihydro-2H-chromen-4-ol + NAD+
-
?
(3S,4R)-trans-isoflavan-4-ol + NADH + H+ + O2
-
Pseudomonas oleovorans KF707 (3S,4R)-3-(7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-yl)-3,4-dihydro-2H-chromen-4-ol + NAD+
-
?
(3S,4S)-cis-isoflavan-4-ol + NADH + H+ + O2
-
Pseudomonas oleovorans (3S,4S)-3-(7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-yl)-3,4-dihydro-2H-chromen-4-ol + NAD+
-
?
biphenyl + NADH + H+ + O2
-
Pseudomonas oleovorans 2,3-dihydro-dihydroxybiphenyl + NAD+
-
?
biphenyl + NADH + H+ + O2
-
Pseudomonas oleovorans KF707 2,3-dihydro-dihydroxybiphenyl + NAD+
-
?
isoflavone + NADH + H+ + O2
-
Pseudomonas oleovorans isoflavone-cis-(2'R,3'S)-dihydrodiol + NAD+
-
?
additional information BDO shows stereoselective preference to the stereoisomers of isoflavan-4-ol in the order (3S,4S)-cis-isoflavan-4-ol > (3R,4S)-transisoflavan-4-ol > (3S,4R)-trans-isoflavan-4-ol > (3R,4R)-cisisoflavan-4-ol Pseudomonas oleovorans ?
-
?
additional information BDO shows stereoselective preference to the stereoisomers of isoflavan-4-ol in the order (3S,4S)-cis-isoflavan-4-ol > (3R,4S)-transisoflavan-4-ol > (3S,4R)-trans-isoflavan-4-ol > (3R,4R)-cisisoflavan-4-ol Pseudomonas oleovorans KF707 ?
-
?

Synonyms

Synonyms Comment Organism
BDO
-
Pseudomonas oleovorans
biphenyl dioxygenase
-
Pseudomonas oleovorans

Cofactor

Cofactor Comment Organism Structure
NADH
-
Pseudomonas oleovorans