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Literature summary for 1.11.1.10 extracted from
- Kinetics of epoxidation by a Musa paradisiaca chloroperoxidase (2019), Int. J. Chem. Kinetics, 51, 602-609 .
No PubMed abstract available
Application
| Application | Comment | Organism |
|---|---|---|
| synthesis | Musa paradisiaca plant juice chloroperoxidase is a potential biocatalyst for organic epoxidation reactions | Musa x paradisiaca |
KM Value [mM]
| KM Value [mM] | KM Value Maximum [mM] | Substrate | Comment | Organism | Structure |
|---|---|---|---|---|---|
| additional information | - |
additional information | steady-state kinetic analysis of epoxidation reactions, detailed overview. Michaelis-Menten and double reciprocal plots for enzymatic epoxidation of indene in the presence of H2O2 using variable indene or t-butyl peroxide concentration | Musa x paradisiaca |
Localization
| Localization | Comment | Organism | GeneOntology No. | Textmining |
|---|---|---|---|---|
| extracellular | - |
Musa x paradisiaca | - |
- |
Organism
| Organism | UniProt | Comment | Textmining |
|---|---|---|---|
| Musa x paradisiaca | - |
- |
- |
Substrates and Products (Substrate)
| Substrates | Comment Substrates | Organism | Products | Comment (Products) | Rev. | Reac. |
|---|---|---|---|---|---|---|
| additional information | epoxidations of indene, styrene, 2-chlorostyrene, 3-chlorostyrene, 4-chlorostyrene, 4-bromostyrene, and naphthalene using Musa paradisiaca plant juice chloroperoxidase in the presence of H2O2 and t-butyl peroxide as oxidants. The yield of styrene oxide in the presence of H2O2 is 44%. The relative affinities of the enzyme for these substrates are in the following order: styrene < 4-chlorostyrene < 3-chlorostyrene < 2-chlorostyrene. Epoxidation by heme chloroperoxidase is the most convenient and promising enzymatic process | Musa x paradisiaca | ? | - |
- |
 |
Synonyms
| Synonyms | Comment | Organism |
|---|---|---|
| chloroperoxidase | - |
Musa x paradisiaca |
| CPO | - |
Musa x paradisiaca |
Temperature Optimum [°C]
| Temperature Optimum [°C] | Temperature Optimum Maximum [°C] | Comment | Organism |
|---|---|---|---|
| 25 | - |
epoxidation reaction | Musa x paradisiaca |
pH Optimum
| pH Optimum Minimum | pH Optimum Maximum | Comment | Organism |
|---|---|---|---|
| 6.2 | - |
epoxidation reaction | Musa x paradisiaca |
Cofactor
| Cofactor | Comment | Organism | Structure |
|---|---|---|---|
| heme | - |
Musa x paradisiaca | |
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Release 2023.1 (January 2023)
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